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- Keywords Palladium complexes;Butynediol;Catalysis;Hydrogenation; 钯络合物;丁炔二醇;催化;加氢;
- Keywords palladium complex;copper complex;styrene;ethylene;carbon monoxide;copolymerization;polyketone; 钯配合物;铜配合物;苯乙烯;乙烯;一氧化碳;共聚;聚酮;
- Keywords palladium complex catalyst;carbon monoxide and ethylene copolymerization;polyketone; 钯络合物催化剂;一氧化碳和乙烯共聚;聚酮;
- Keywords palladium complex catalyst;catalytic hydrogenation;Raney nickle-palladium complexcatalyst.; 钯络合催化剂;镍一钯复合催化剂;催化氢化;
- The oxidative carbonylation of phenol to DPC catalyzed by palladium complexes catalyst system (PdCl2+ Cu(OAc)2+ TBAB+ H2BQ) has been studied. 开发出了苯酚氧化羰基化直接合成碳酸二苯酯钯系络合物催化体系:PdCl_2+Cu(OAc)_2+TBAB+H_2BQ;
- Two different kinds of palladium complexes of nitrogen containing polymere havebeen prepared and their catalytic actions for p -nitro -methyl benzfene have been invertigeted. 制备了两种不同的含氮高分子-钯络合物,并研究了它们对对硝基甲苯的催化活性。
- Woolsupported palladium complex was synthesized and characterized by XPS and IR. 用XPS、IR方法对羊毛-钯络合物进行了初步表征。
- METHODS The target compound was synthesized from cross-coupling reaction catalyzed by P, O chelate palladium complex. 方法用P,O双齿螯合钯配合物催化偶联反应合成目标化合物。
- The mechanism of the palladium complex 40 catalyzed Suzuki cross-coupling reaction was discussed. The cause of decomposition of catalyst and appearance of palladium black were studied. 探讨了cis-Pd(Ph_2PCH_2COO)_2(40)催化Suzuki偶联反应机理及催化剂分解析出钯黑的原因。
- A new mathod is studied for the synthesis of diketones with the crosscoupling reaction of organotin reagents and diacyl chlorides catalyzed by cellulose oxyphosphine palladium complex compound. 本文首次采用纤维素氧膦-钯络合物为催化剂,以丙酮为溶剂,有机锡试剂与二元酰氯偶联合成二元酮化物。
- Keywords palladium;lowe-Pd alloy;recovery; 钯;低钯合金;回收;
- This paper presents the cross\|coupling reaction of organotins with substituted cinnamoyl chlorides catalyzed by cellulose oxyphosphine palladium complex for the synthesis of chalcones. 报道了采用纤维素氧膦-钯络合物为催化剂,有机锡试剂与取代肉桂酰氯进行交叉偶联合成查耳酮化合物。
- The cellulose oxyphosphine palladium complex catalyst was prepared and the catalytic activity of catalyst in the cross - coupling reaction of tributyltin hydride with acid chlorides was investigated. 制备了纤维素氧瞵-钯配合物催化剂,详细考察了催化剂对三(正)丁基锡氢化物和酰卤化合物偶联反应的催化作用。
- Keywords chitosan;palladium complex;catalytic;p-nitroanisole; 壳聚糖;钯配合物;催化性能;对硝基苯甲醚;
- The catalytic action of cellulose oxyphosphine palladium complexs in the crosscoupling reaction of organotin reagents with acid chlorides for forming C-C bond is presented. 报道了纤维素氧膦-钯配合物在有机锡试剂与酰氯化合物形成碳-碳键的交叉偶联反应中的催化作用,并对部分反应条件及反应机理进行了研究和探讨。
- Keywords Palladium(II) complex;Hydroxyethyl pendant;Crystal structure; 钯(II)配合物;羟乙基臂;晶体结构;
- Keywords palladium(II);ternary complex;DNA;intercalation;anticancer activity; 钯(II);三元配合物;DNA;插入作用;抗癌活性;
- Keywords palladium;amidocarbonylation;amino acid;N-acyl amino acid; 钯;酰胺羰基化;氨基酸;N酰基氨基酸;
- Keywords palladium;solvent sublation;spectrophotometry; 钯;溶剂浮选;分光光度法;
- Keywords palladium;alkynes;diynes;conjugated enynes;aromatization; 钯;炔烃;双炔;共轭烯炔;芳构化;